Methodology of hydrogeological characterization of deep carbonate aquifers as potential reservoirs of groundwater. Case of study: the Jurassic aquifer of <Emphasis Type="Italic">El Maestrazgo</Emphasis> (Castellón,Spain)     

M. Mejías  J. Garcia-Orellana  J. L. Plata  M. Marina  E. Garcia-Solsona  B. Ballesteros  P. Masqué  J. López  C. Fernández-Arrojo 《Environmental Geology》2008,54(3):521-536

A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (¹⁸O, ²H and ³H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system. Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater uses in the area of study.  相似文献   

四川大陆槽稀土矿床碳酸岩-英碱正长岩锆石U-Pb年代学和Hf同位素性质及其地质意义   总被引：5，自引：2，他引：3  

田世洪  侯增谦  杨竹森  杨志明  袁忠信  王彦斌  谢玉玲  刘英超  李政 《岩石学报》2008,24(3)

川西冕宁-德昌稀土成矿带是中国最重要的稀土成矿带之一,所有稀土矿床均与碳酸岩-正长岩杂岩体有关.前人研究表明,牦牛坪、木落寨和里庄碳酸岩-碱性杂岩体成岩年龄与其相应矿床的成矿年龄基本一致,而大陆槽正长岩年龄与REE矿床的成矿年龄相差甚远.本文对大陆槽碳酸岩、英碱正长岩进行了SHRIMP U-Pb锆石年代学和LA-MC-ICPMS锆石Hf同位素原位测量,它们的形成年龄分别为12.99±0.94Ma、14.53±0.31Ma,表明两者是同时形成的,且与其成矿年龄基本一致.碳酸岩和正长岩的εHf(t)值、Hf模式年龄与它们的εNd(t)值、Nd模式年龄所展现出来的特征一致,说明在其形成过程中有地壳物质的加入.  相似文献   

铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成   总被引：22，自引：5，他引：17  

朱祥坤  李志红  赵新苗  唐索寒  何学贤  Nick S. Belshaw 《岩石矿物学杂志》2008,27(4):263-272

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).  相似文献   

安徽铜陵朝山金矿床流体包裹体研究   总被引：3，自引：1，他引：2  

杨小男  徐兆文  高庚  陆现彩  刘苏明  李海勇 《岩石学报》2008,24(8)

朝山金矿床是狮子山矿田内的热液交代型金矿床,在成因上与燕山期的白芒山辉石闪长岩有关.通过采集发育在不同深度下的含金黄铁矿-石英一方解石脉样品,进行流体包裹体岩相学观察和显微测温发现,石英和方解石中均捕获了富气相、富液相的两相水溶液包裹体和含子晶的三相水溶液包裹体,以上三种类型包裹体的均一温度统计峰值分别出现于315～335℃和255～275℃,盐度的统计峰值出现于17.50%～22.50%NaCl eq.和32.50%～37.50%NaCl eq.之间.激光拉曼探针分析表明,石英中流体包裹体的气相成分以水蒸汽为主,伴有少量CO2,可能含有CH4.流体的H、O同位素组成具确岩浆水特征.上述研究表明.朝山金矿成矿流体经历了相态变化,发生了不均匀捕获.受燕山期岩浆作用影响,狮子山矿田内的铜、金成矿在时空上具有一定联系,成矿流体运移的过程中,主要发生了相分离、气相液化和减压沸腾作用,可能是形威铜、金矿化分带的重要原因.  相似文献   

冲绳海槽有孔虫壳体的微量元素Sr,Nd同位素地球化学   总被引：6，自引：1，他引：6  

孟宪伟  杜德文  程振波 《海洋学报》2001,23(2):62-68

钙质生物壳的微量元素组合和Sr,Nd同位素组成是识别海底混合源沉积物中生物源物质相对贡献的重要参数.冲绳海槽有孔虫壳体强烈富集Sr,P,Mn和Ba,富集Li,U,Th,Sc,Co,Pb,Zn,Cr,Rb,Y,Sb和轻稀土元素,弱富集V,Ga,Zr,Nb,Cd和中稀土元素,相对贫Ge,Mo,In,Sn,Cs,Hf,Ta,W,Tl,Bi和重稀土元素,海水中微量元素的背景含量和生物活动对微量元素的选择性吸收是有孔虫壳体中微量元素发生富集和贫化的主要机制,冲绳海槽有孔虫壳体的稀土元素配分模式与海水和太平洋有孔虫的有明显差异,表现出中稀土元素相对富集,并具有微弱的负Ce异常.有孔虫壳体的Sr,Nd同位素比值也与大洋海水不同,分别为0.709769和0.512162,前者略高于大洋海水,后者略低于大洋海水,表明冲绳海槽海水明显受大陆河水影响.  相似文献   

中太平洋铁锰结壳铅同位素研究   总被引：5，自引：0，他引：5  

周枫  凌洪飞  陆尊礼  蒋少涌 《海洋地质与第四纪地质》2005,25(1):55-62

已有研究表明大洋中溶解的铅(Pb)来源于陆源物质，但是，对Pb进入大洋的途径争议很大。为此分析了取自中太平洋两块铁锰结壳样品的Pb同位素组成，获得了整个新生代的中太平洋Pb同位素演化历史。结果表明这两块结壳的Pb同位素随时间的演化曲线与中北太平洋沉积物岩心LL44-GPC3中风成碎屑的Pb同位素演化曲线相似。证实该区深水中的天然溶解铅主要来自风成粉尘，并且50Ma之前中太平洋中溶解Pb同位素组成主要取决于源自美洲的风成粉尘的输入，40Ma之后主要取决于源自亚洲的风成粉尘的输入。  相似文献   

Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions   总被引：6，自引：1，他引：6  

Miguel A. Goni  Mary W. Cathey  Yong H. Kim  George Voulgaris 《Estuarine, Coastal and Shelf Science》2005,63(4):683-700

Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ¹³C_POC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C₃ plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C₄ vegetation (Spartina alterniflora) and/or marine phytoplankton.  相似文献   

Organic matter origin and distribution in suspended particulate materials and surficial sediments from the western Adriatic Sea (Italy)   总被引：5，自引：2，他引：5  

T. Tesi  S. Miserocchi  M.A. Goi  L. Langone  A. Boldrin  M. Turchetto 《Estuarine, Coastal and Shelf Science》2007,73(3-4):431-446

In this study, organic carbon (OC), total nitrogen (TN), stable carbon isotopic (δ¹³C_OC) and CuO reaction product compositions were used to identify the sources of organic matter (OM) and to quantify the relative importance of allochthonous and autochthonous contributions to the western Adriatic Sea, Italy. Suspended particulate material (195 samples) and surficial sediments (0–1 cm, 70 samples) from shallow cross-shelf transects were collected in February and May 2003, respectively. Vertical water column profiles were acquired along the same transects. Data include depth, potential temperature, salinity, density and chlorophyll fluorimetry.Along the western Adriatic shelf in the near-shore region, the phytoplankton growth was influenced by dynamics of the buoyant plumes from the Po and Appennine rivers. A small amount of very fine terrigenous material remained suspended within the coastal current and was exported southward along the shelf to the slope. High variability in the bulk composition was detected in the Po prodelta surficial sediments, whereas the western Adriatic shelf, although a larger area, exhibited a narrower range of values.A significant decoupling was observed between suspended particles in the water column and surficial deposits. The organic material collected in the water column was compositionally heterogeneous, with contributions from marine phytoplankton, riverine–estuarine phytoplankton and soil-derived OM. Frequent physical reworking of surficial sediments likely leads to the efficient oxidation of marine OC, resulting in the observed accumulation and preservation of refractory soil-derived OC delivered by the Po and Appennine rivers.  相似文献   

长江河口硼的测定及分布规律研究     

韩庆平  吴玲  奚建风  陈邦林 《海洋科学》1997,21(2):35-38

采用ＨＰＴＡ方法对长江口水中硼进行分析，并与姜黄素法进行比较，方法的标准偏差为０．００５，变动系数小于５％，对长江口水样分析结果与姜黄素法相比较，其相对误差为－０．４％。  相似文献   

Measurement of ²²⁴Ra, ²²⁶Ra and ²²⁸Ra in seawater using Mn-fiber adsorption-γ spectrum method   总被引：2，自引：1，他引：2  

Liu Guangshan  Huang Yipu  Chen Xinbao 《海洋学报(英文版)》2000,19(2):19-27

I~IOXThe half-lives of natural radioactive nuclides "'Ra, 226Ra and 228Ra are 3. 66 d, 5. 76 a,1600 a respectively, hence, the marine process with various time scales can be researched by taking these nuclides as tracers. Because these nuclides can be determined by measuring them or theirdaughters' a,g, y-rays, they have been applied extensively in oceanography research. Huang(1996), Huang et al. (1996 a,b) and Chen (1996) have given reviews on it.Since the contents of "'Ra, 226Ra and 228…  相似文献